This particular smoking jacket is made of wool challis with a wool flannel lining quilted with lambswool. Animal products like wool and hides "breathe." That's what makes them comfortable in all kinds of weather; they keep you really warm in cold weather, and they don't make you sweat in hot weather. They "breathe." Faux leather simply is not a substitute for the real thing - looks the same, but, baby, it ain't! Ditto for a lot of modern fabrics.
Wool challis was first woven in the mid-1800's in London. It would have been new, and therefore fashionable, during Civil War times. One of it's greatest properties is that it could be "printed" on with small, multi-colored patterns. It also draped well, had a softness of feel, but most importantly, it was easily cared for. So folks wanting to show their wealth would appreciate being seen by other men in a brightly decorated smoking jacket. Also, formal dress was common at dinner and, when retiring to the study, smoking jackets prevented ashes and smoking odors from ruining the formal attire.
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Their cigars were kept in small cigar holders/cabinets.
Humidors decorated with animals of the hunt would hold pipe tobacco.
Then it's down to the basement for some displays of photos, artifacts, and information.
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